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  • Ferroalloy piezoceramic material based on PZT, electrophysical and mechanical properties in a wide temperature range

    The electrophysical and mechanical properties of a piezoceramic material based on CTS are investigated. A number of features in the behavior of the electrophysical properties of the material in the temperature range located significantly below the low-frequency (1 kHz) maximum of the dielectric constant T_m = 160℃ have been revealed. The obtained results indicate the proximity of the studied material to ferroelectric relaxors, in particular, the low coercive field E_c~5 kVcmcm, the significant dependence of T_m on the frequency and amplitude of the measuring field, as well as the behavior of the velocity of longitudinal ultrasonic waves in this ceramic. It is shown that the elastic properties of this material are very close to ferroelectric relaxors, having a high malleability in a very wide temperature range. At the same time, the squareness of the polarization loops at relatively low temperatures indicates the manifestation of the classical properties of the ferroelectric during the polarization switching processes, and not the "freezing" processes characteristic of ferroelectric relaxors. From the results obtained, it can be established that this composition will be promising for use in the actuators of adaptive optics systems and precision positioning devices due to the high values of piezomodules.

    Keywords: PZT system, ferroalloy ceramics, dispersion, polarization, elastic properties, blurred phase transitions, curie temperature, depolarization temperature, ferroelectric relaxor, rhombohedral phase, tetragonal phase