The synthesis of nanocomposite FeNi3/C based on the PAN, FeCl3 · 6H2O and NiCl2 · 6H2O, whereby the first time by the IR heating at 400 ÷ 700 ° C obtained nanocomposite FeNi3/C FeNi3 particle size of 10 to 80 nm are uniformly distributed UM. Using thermodynamic calculations based on the minimization of the Gibbs energy, confirmed the synthesis of nanocomposite FeNi3/C at T=400 ° C reduction of Fe and Ni with H2, produced during the process of carbonization of polyacrylonitrile with infrared heating. Designed as a nano material of the films can be effectively used as a carrier material for a magnetic information recording superdense. Recording density is achieved in such a carrier (85-100) Gb/dyuym2.
Keywords: nanocomposite, polyacrylonitrile, infrared heating, recording information, the magnetic properties, the carbon matrix
The coloration centres (CC) in crystals of rear earth gallium garnets (REGG): Gd3Ga5O12 (GGG), Gd3Sc1,6Ga3,4O12 (GSGG) и Nd3Ga5O12 (NGG) obtained by Chohraljskiy method, were investigated by methods of optical spectroscopy and spectral analysis in the wavelength range of 0,2-0,87 microns. In the case of keeping the samples under dark conditions, unstable CC were formed in the crystals of GGG and GSGG. The absorption maxima are at λmax1 = 0,243 m and λmax2 = 0,275 m at concentration of N ~ 1018 cm-3. It is suggested that the observed enlightenment is caused by the recharging of growth defects and occurring the energy levels in the band gap of garnets. It appears that these CC correspond to centres of O- holes, originated from gallium vacancies V3-Ga 3+ in tetrahedral and octahedral nots which form near clusters of [V3-Ga 3+ - V2+O2- ]
Keywords: color centers, rare earth gallium garnets, kristylly, Czochralski method, the crystal lattice